新和成(002001):乙氧甲叉MSDS

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生意社2010年06月18日讯

SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

MSDS Name: Diethyl Ethoxymethylenemalonate, 99+%
Synonym: Ethoxymethylenmalonic Acid Diethylester
Company: AboutChem.com

SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS# Chemical Name % EINECS#
87-13-8 Diethyl Ethoxymethylenemalonate 99+% 201-725-7
©2010.7 生意社-医药化工研究中心 cp.toocle.com

Hazard Symbols: XN
Risk Phrases: 42/43

SECTION 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
May cause sensitization by inhalation and skin contact.

Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

SECTION 4 - FIRST AID MEASURES

Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Ingestion Get medical aid.
Notes to Physician:

SECTION 5 - FIRE FIGHTING MEASURES

General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.

SECTION 7 - HANDLING and STORAGE

Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.

SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 87-13-8:

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 279.0 - 281.0 deg C @ 760.00m
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 144 deg C ( 291.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >279 deg C
Solubility in water: insoluble
Specific Gravity/Density: 1.0800g/cm3
Molecular Formula: C10H16O5
Molecular Weight: 216.23

SECTION 10 - STABILITY AND REACTIVITY

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, acids, bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

SECTION 11 - TOXICOLOGICAL INFORMATION

RTECS#:
CAS# 87-13-8: OO1100000
LD50/LC50:
CAS# 87-13-8: Draize test, rabbit, skin: 500 mg/24H Moderate; Oral,mouse: LD50 = 2227 mg/kg; Oral, rat: LD50 = 925 mg/kg.
Carcinogenicity:
Diethyl Ethoxymethylenemalonate -Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

SECTION 12 - ECOLOGICAL INFORMATION

SECTION 13 - DISPOSAL CONSIDERATIONS

Dispose of in a manner consistent with federal, state, and local regulations.

SECTION 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

SECTION 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 42/43 May cause sensitization by inhalation and skin contact.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 27 Take off immediately all contaminated clothing.
WGK (Water Danger/Protection)
CAS# 87-13-8: 1
Canada
CAS# 87-13-8 is listed on Canada's NDSL List.
CAS# 87-13-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 87-13-8 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION

MSDS Creation Date: 3/04/1998 Revision #2 Date: 12/03/2002

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

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文章关键词:乙氧甲叉 新和成 医药中间体
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